Synthesized and Designed New Modified Poly(vinyl chloride) Structures to Enhance Their Photo-Resistance Characteristics
نویسندگان
چکیده
We synthesized and designed four new modified poly(vinyl chloride) structures to develop various polymer derivatives enhance their photo-stability. Commercially available was synthetically into a containing aromatic Schiff base moieties. First, the PVC reacted with ethylene diamine from one side by using an equivalent of extra increase probability preventing cross-linking versus two-sided reaction. In second step, corresponding aldehydes were amino group create molecules. Different approaches applied confirm polymers such as FTIR, 1H NMR, EDX. Using these methods, percentage modification for studied materials demonstrated. The exhibited between 30–35% integration in NMR spectra EDX analytical composition elements. order lessen photo-degradation polymeric chains, synthetic compounds have been employed photo-stabilizers films. assess effectiveness photo-stabilizer, variety techniques used, including weight loss method monitoring development different functional groups while being exposed radiation FTIR spectra. Utilizing atomic force microscopy (AFM), scanning electron (SEM), microscope pictures, surface morphology produced also investigated. These experiments demonstrated that novel perform excellent comparison pure PVC. As result, after UV light 300 h, films exhibit less than blank PVC, so range may be absorbed connected units’ high conjugation mechanism.
منابع مشابه
Medical-grade Polyvinyl Chloride Modified with Crystal Violet and Montmorillonite
Bacterial colonization of polymeric medical aids causing so-called nosocomial infections is one of the main problems linked with the extensive use of polymeric devices in clinical applications. In this study, the properties of medical-grade polyvinyl chloride were modified by incorporating crystal violet into its bulk structure. Sodium montmorillonite was used as a carrier for the crystal viole...
متن کاملVinyl chloride and polyvinyl chloride exposure and occupational lung disease.
S everal recent reports,12 and one in this issue (see page 828), have contributed new observations on pulmonary disease in vinyl chloride (VC ) -and polyvinyl chloride (PVC) -exposed patients. Earlier reports, a few even preceding the identification in 1974 of vinyl chloride as a human carcinogen (with hemangiosarcoma of the liver the marker tumor, but most probably not the only tumor), had cen...
متن کاملThermal Degradation of Polyvinyl Chloride
A survey is given of the recent advances in the study of and the present knowledge of the thermal degradation of polyvinyl chloride. The sites for initiation of the thermal degradation, the mechanism of the dehydrochiorination, the discolouration of PVC by heat and the influence of plasticizers on the rate of degradation are discussed.
متن کاملEnvironmental Impacts of Polyvinyl Chloride
This report was prepared by the author and does not represent the opinions of The University of Oregon or any of its affiliates. p. 53 © Basel Action Network. PVC coated wire waste sorted and burned by villagers in Guiyu, China. Cancer causing polycyclic aromatic hydrocarbons and dioxins will result from burning wires made from PVC and brominated flame retardants. p. 77 © Bryce lankard/Greenpea...
متن کاملIncidence of cancer among vinyl chloride and polyvinyl chloride workers.
The results of a follow up study of the incidence of cancer and the mortality in a cohort of 454 male workers producing vinyl chloride and polyvinyl chloride are presented. The study population was restricted to employees with more than one year's work experience in the study plant between 1950 and 1969 and the cohort was followed up from 1953 to the end of 1979. Twenty three new cases of cance...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemistry
سال: 2022
ISSN: ['2624-8549']
DOI: https://doi.org/10.3390/chemistry4040075